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| 研究業績（1990〜） |
1. 原著論文
Akihiro Yoshida, Yoshinao Nakagawa, Kazuhiro Uehara, Shiro Hikichi, Noritaka Mizuno
“Inorganic Cryptand: Size-Selective Strong Metallic Cation Encapsulation
by a Disilicoeicosatungstate (Si2W20) Polyoxometalate”
Angew. Chem. Int. Ed., 48, 7055-7058 (2009).
Koyu Fujita, Munetaka Akita, Shiro Hikichi
“Acetoxybis(imidazolyl)methylborate [B(ImN-Me)2(OC(=O)Me)Me]-: Carboxylation of borane moiety of imidazolyl-based scorpionate”
Inorg. Chim. Acta, 362, 4472-4479 (2009).
Shiro Hikichi, Mami Kaneko, Yasuyuki Miyoshi, Noritaka Mizuno, Koyu Fujita, Munetaka
Akita
“Design, Synthesis, and Catalysis of Bio-inspired Immobilized Metallocomplex
Catalyst”
Top. Catal., 52, 845-851 (2009).
Shiro Hikichi, Hideho Okuda, Yoshiko Ohzu, Munetaka Akita
“Structural Characterization and Oxidation Activity of a Nickel(II) Alkylperoxo
Complex”
Angew. Chem. Int. Ed., 48, 188-191 (2009).
Sayaka Uchida, Shiro Hikichi, Takeo Akatsuka, Toshiyuki Tanaka, Ryosuke Kawamoto, Aldes Lesbani, Yoshinao Nakagawa, Kazuhiro Uehara, Noritaka Mizuno
“Preparation of Monodispersed Nano-particles by Electrostatic Assembly
of Keggin-type Polyoxometalates and tacn-Based Transition Metal Complexes”
Chem. Mater., 19, 4694-4701 (2007).
Akihiro Yoshida, Shiro Hikichi, Noritaka Mizuno
“Baeyer-Villiger Oxidation and C-C Bond Formation Reactions Catalyzed by
Disilicoeicosatungstates”
Stud. Surf. Sci. Catal., 172, 205-208 (2007).
Akihiro Yoshida, Shiro Hikichi, Noritaka Mizuno
“Acid-Base Catalyses by Dimeric Disilicoicosatungstates and Divacant γ-Keggin-type
Silicodecatungstate Parent: Reactivity of the Polyoxometalate Compounds
Controlled by Step-by-step Protonation of Lacunary W=O Sites”
J. Organomet. Chem., 692, 455-459 (2007).
Keigo Kamata, Miyuki Kotani, Kazuya Yamaguchi, Shiro Hikichi, Noritaka Mizuno
“Olefin Epoxidation with Hydrogen Peroxide Catalyzed by Lacunary Polyoxometalate [γ-SiW10O34(H2O)2]4-”
Chem. -Eur. J., 13, 639-648 (2007).
Kazuhiro Uehara, Hideaki Nakao, Ryosuke Kawamoto, Shiro Hikichi, Noritaka Mizuno
“2D-Grid Layered Pd-Based Cationic Infinite Coordination Polymer/Polyoxometalate
Crystal with Hydrophilic Sorption”
Inorg. Chem., 45, 9448-9453 (2006).
Udai P. Singh, Asish K. Sharma, Shiro Hikichi, Hidehito Komatsuzaki, Yoshihiko Moro-oka, Munetaka Akita
“Hydrogen bonding interaction between imidazolyl N-H group and peroxide:
Stabilization of Mn(III)-peroxo complex TpiPr2Mn(η2-O2)(imMeH) (imMeH = 2-methylimidazole)”
Inorg. Chim. Acta, 359, 4407-4411 (2006).
Akihiro Yoshida, Masayuki Yoshimura, Kazuhiro Uehara, Shiro Hikichi, Noritaka Mizuno
“Formation of S-Shaped Disilicoeicosatungstate (W20) and the Efficient Baeyer-Villiger Oxidation with Hydrogen Peroxide”
Angew. Chem. Int. Ed., 45, 1956-1960 (2006).
Yuya Goto, Keigo Kamata, Kazuya Yamaguchi, Kazuhiro Uehara, Shiro Hikichi, Noritaka Mizuno
“Synthesis, Structural Characterization, and Catalytic Performance of Dititanium-substituted γ-Keggin Silicotungstate”
Inorg. Chem., 45, 2347-2356 (2006).
Kazuhiro Uehara, Shiro Hikichi, Akiko Inagaki, Munetaka Akita
“Xenophilic Complexes Bearing a TpR Ligand, TpRM-M'Ln [TpR = TpiPr2, Tp# (TpMe2,4-Br); M= Ni, Co, Fe, Mn; M'Ln= Co(CO)4, Co(CO)3(PPh3), RuCp(CO)2]: The Two Metal Centers are Held Together not by Covalent Interaction
but by Electrostatic Attraction.”
Chem. -Eur. J., 11, 2788-2809 (2005).
Sayaka Uchida, Ryosuke Kawamoto, Takeo Akatsuka, Shiro Hikichi, Noritaka Mizuno
“Structures and Sorption Properties of Ionic Crystals of Macrocation-Dawson-type Polyoxometalates with Different Charges”
Chem. Mater., 17, 1367-1375 (2005).
Yoshiaki Takahashi, Mariko Hashimoto, Shiro Hikichi, Yoshihiko Moro-oka, Munetaka Akita
“Oxygenation of a Low Valent Rhodium Complex, TpiPr2Rh(dppe): Sequential Conversion of Molecular Oxygen into Peroxo and Hydroperoxo Complexes and Characterization of the Peroxo Species”
Inorg. Chim. Acta, 357, 1711-1724 (2004).
Yoshiaki Takahashi, Shiro Hikichi, Yoshihiko Moro-oka, Munetaka Akita
“Oxygenation of a Series of Cationic Aquoruthenium Complexes, TpiPr2Ru(OH2)nL3-nCF3SO3(THF)x, Leading to Mono- and Dinuclear Aquo-hydroxo Complexes Supported by Unique
Hydrogen Bonding Networks”
Polyhedron, 23, 225-234 (2004).
Yan Xu, Wei Fan, Naotaka Chino, Kazuhiro Uehara, Shirou Hikichi, Noritaka Mizuno, Masaru Ogura, Tatsuya Okubo
“The Hydrothermal Synthesis and Crystal Structure of (H2O)[Ge5O10] and [(CH3)4N][Ge10O20OH], Two Novel Porous Germanates”
Chem. Lett., 33, 74-75 (2004).
Keigo Kamata, Kazuya Yamaguchi, Shiro Hikichi, Noritaka Mizuno
“[{W(=O)(O2)2(H2O)}2(μ-O)]2--Catalyzed Epoxidation of Allylic Alcohols in Water with High Selectivity and Utilization of Hydrogen Peroxide”
Adv. Synth. Catal., 345, 1193-1196 (2003).
Ken-ichiro Sugawara, Shiro Hikichi, Munetaka Akita
“A Peroxochromium Complex, TpiPr2Cr(O2)2, Obtained by Oxidative Dehydrative Condensation Between a Dihydroxochromium Complex and H2O2 [TpiPr2 = hydrotris(3,5-diisopropylpyrazolyl)borato]”
Dalton Trans., 4346-4355 (2003).
Masato Kujime, Shiro Hikichi, Munetaka Akita
“Interaction of Hyddroperoxopalladium Complexes, (TpR)(py)Pd-OOH, with Hydroxonickel and -cobalt Complexes, [(μ-OH)(MTpR’)]2 (M = Ni, Co), Leading to Oxidative Dehyddrogenation of the Saturated Hydrocarbyl Moiety in the Ancillary Ligand (TpiPr2)”
Dalton Trans., 3506-3515 (2003).
Masato Kujime, Shiro Hikichi, Munetaka Akita
“Enolato-cobalt and -nickel Complexes Bearing TpiPr2 Ligand, [TpiPr2M(XCHY)]n [TpiPr2 = Hydrotris(3,5-diisopropylpyrazolyl)borato; n= 1, 2], Obtained from Hydroxometal
Complexes, (μ-OH)2(MTpiPr2)2, and Active Methylene Compounds, CH2XY”
Inorg. Chim. Acta, 350, 163-174 (2003).
Masato Kujime, Shiro Hikichi, Munetaka Akita
“Conversion of a Hydroperoxo Complex, (TpiPr2)(py)Pd-OOH, into a Cyclic Alkylperoxo Complex Catalyzed by Cu(II) Species
[TpiPr2: Hydrotris(3,5-diisopropylpyrazolyl)borato]”
Chem. Lett., 32, 486-487 (2003).
Keigo Kamata, Koji Yonehara, Yasutaka Sumida, Kazuya Yamaguchi, Shiro Hikichi, Noritaka Mizuno
“Efficient Epoxidation of Olefins with >99% Selectivity and Use of Hydrogen Peroxide”
Science, 300, 964-966 (2003).
Ken-ichiro Sugawara, Shiro Hikichi, Munetaka Akita
“Di- and Trivalent Chlorochromium Complexes Bearing Hydrotris(3,5-diisopropylpyrazolyl)borato
Ligand (TpiPr2), TpiPr2CrCln(L) (n= 1,2) and [TpiPr2Cr(μ-Cl)]2: Flexible Coordination Behavior of the TpiPr2 Ligand and Reduction Features of Cr(II) Species”
J. Chem. Soc., Dalton Trans., 4514-4524 (2002).
Kazuhiro Uehara, Shiro Hikichi, Munetaka Akita
“Reactivity Control of a Dinuclear Xenophilic Species, Tp#Ni-RuCp(CO)2, via Spin Crossover across a Metal-metal Bond [Tp#: Hydrotris(3,5-dimethyl-4-bromopyrazolyl)borato]”
Chem. Lett., 31, 1198-1199 (2002).
Taichi Miyaji, Masato Kujime, Shiro Hikichi, Yoshihiko Moro-oka, Munetaka Akita
“Synthesis and Characterization of a Series of Hydroperoxo-, Alkylperoxo- and μ-Peroxo-palladium Complexes Containing Hydrotris(3,5-diisopropylpyrazolyl)borato Ligand (TpiPr2), (TpiPr2)(py)Pd-OO-X [X= H, t-Bu, Pd(TpiPr2)(py)] and (TpiPr2)(py)Pd-(μ-η1:η2-OO)-PdTpiPr2”
Inorg. Chem., 41, 5286-5295 (2002).
Kazuhiro Uehara, Shiro Hikichi, Munetaka Akita
“Highly Labile Cationic Tris-acetonitrile complexes, [TpRM(NCMe)3]OTf (M= Ni, Co; TpR: Hydrotrispyrazolylborato, R= Ph,Me and iPr2): Versatile Precursors for TpR-containing Nickel and Cobalt Complexes”
J. Chem. Soc., Dalton Trans., 3529-3538 (2002).
Shin-ichi Yoshimitsu, Shiro Hikichi, Munetaka Akita
“Synthesis and Characterization of Coordinatively Unsaturated Alkynyl-
and Aryl-cobalt Complexes with 15 Valence Electrons, TpiPr2Co-R, Bearing Hydrotris(3,5-diisopropylpyrazolyl)borato Ligand (TpiPr2)”
Organometallics, 21, 3762-3773 (2002).
Shiro Hikichi, Yasuyuki Sasakura, Michito Yoshizawa, Yoshiko Ohzu, Yoshihiko Moro-oka,
Munetaka Akita
“Selective Synthesis, Characterization, and Configurational Flexibility of the Coordinatively Unsaturated Metal Center of Half-sandwich Type Complexes with the Less-Hindered Hydrotris(3,5-dimethyl-4-X-1-pyrazolyl)borate Ligands [TpMe2,XMII(κ2-O,O-L)] (M = Ni, Co; L = NO3, OAc; X = Me, H, Br)”
Bull. Chem. Soc. Jpn., 75, 1255-1262 (2002).
Shiro Hikichi, Michito Yoshizawa, Yasuyuki Sasakura, Yoshiko Ohzu, Yoshihiko Moro-oka,
Munetaka Akita
“Structural Characterization and Intramolecular Aliphatic C-H Oxidation
Ability of MIII(μ-O)2MIII Complexes of Ni and Co with the Hydrotris(3,5-dialkyl-4-X-pyrazolyl)borate
Ligands TpMe2,X (X = Me, H, Br) and TpiPr2”
Chem. -Eur. J., 7, 5011-5028 (2001).
Ken-ichiro Sugawara, Shiro Hikichi, Munetaka Akita
“Dichloromethane Activation by Chlorochromium(II) Complexes with TpiPr2: Generation of an Electrophilic Cr-Methylene Species without the Action of an External Cl-Abstraction Reagent”
Chem. Lett., 30, 1094-1095 (2001).
Kazuhiro Uehara, Shiro Hikichi, Munetaka Akita
“Rational Synthesis and Reversible Metal-metal Bond Scission of Heterobimetallic
Xenophilic Complexes Containing an Unsupported, Polar Metal-metal Bond,
TpiPr2M-Co(CO)3L (M= Ni, Co, Fe, Mn; L= CO, PPh3)”
Organometallics, 20, 5002-5004 (2001).
Masato Kujime, Shiro Hikichi, Munetaka Akita
“N/O- and C-Bound (Enolato)palladium Complexes with Hydrotris(pyrazolyl)borato Ligands (TpR: R = iPr2, Me2) Obtained via Dehydrative Condensation between the Hydroxo Complexes TpRPd(Py)OH and Active Methylene Compounds: Factors Determining the Isomer Distribution and Dimerization of Cyano Compounds”
Organometallics, 20, 4049-4060 (2001).
Nobuhiko Shirasawa, Trieu Thi Nguyet, Shiro Hikichi, Yoshihiko Moro-oka, Munetaka Akita
“Tetrahedral, Highly Coordinatively Unsaturated 14e (Fe) and 15e (Co) Hydrocarbyl
Complexes Bearing Hydrotris(pyrazolyl)borato Ligands (TpR’), TpR’M-R (M = Fe, Co, Ni)”
Organometallics, 20, 3582-3598 (2001).
Munetaka Akita, Yoshiaki Takahashi, Shiro Hikichi, Yoshihiko Moro-oka
“Synthesis and Dehydrative Condensation of Monomeric Hydroxoruthenium Complexes
with Hydrotris(3,5-diisopropylpyrazolyl)borate Ligand, TpiPr2Ru(L2)(OH) (L2 = dppe, bipy)”
Inorg. Chem., 40, 169-172 (2001).
Udai P. Singh, Rajender Singh, Shiro Hikichi, Munetaka Akita, Yoshihiko Moro-oka
“Characterization of a dinuclear Mn(II) tri(μ-carboxylato) complex with
the hindered hydrotris(3,5-diisopropyl-1-pyrazolyl)borate (= TpiPr2) ligand: intramolecular hydrogen bonding interaction between the protonated TpiPr2 and Mn-coordinating carboxylate ligands”
Inorg. Chim. Acta, 310, 273-278 (2000).
Munetaka Akita, Mariko Hashimoto, Shiro Hikichi, Yoshihiko Moro-oka
“Synthesis and Structural Comparison of TpiPr2Rh[cis-1,2-bis(diphenylphosphino)ethene]: Factors Determining Hapticity
(κ2 vs. κ3) of the TpiPr2 ligand in TpiPr2Rh(diphosphine) Complexes”
Organometallics, 19, 3744-3747 (2000).
Munetaka Akita, Taichi Miyaji, Nobuyuki Muroga, Cordula Mock-Knoblauch, Shiro Hikichi, Waldemar Adam, and Yoshihiko Moro-oka
“Synthesis and Dehydrative Condensation of Square-Planar Mono- and Dinuclear
Hydroxopalladium Complexes with the Hydrotris(3,5-diisopropylpyrazolyl)borato
Ligand (TpiPr2), TpiPr2(Py)Pd-OH, and (μ-OH)2{PdTpiPr2(H2O)}2”
Inorg. Chem., 39, 2096-2102 (2000).
Koyu Fujita, Shiro Hikichi, Munetaka Akita, Yoshihiko Moro-oka
“Synthesis and structural characterization of a new-class of organoborato ligands containing imidazolyl functional groups [MeB(ImN-Me)2(X)]-”
J. Chem. Soc., Dalton Trans., 1255-1260 (2000).
De-qiang Ma, Shiro Hikichi, Munetaka Akita, Yoshihiko Moro-oka
“An entry to half-sandwich complexes of first row transition metals (Ni, Co, Mn) containing the Klaui tripodal ligand, LOMe: synthesis and crystal structures of oligomeric, [LOMeM(μ-X)(L)]n (n = 2, 4), and monomeric complexes, LOMeM(L2)(X)”
J. Chem. Soc., Dalton Trans., 1123-1134 (2000).
Tamako Ogihara, Shiro Hikichi, Munetaka Akita, Takeshi Uchida, Teizo Kitagawa, Yoshihiko Moro-oka
“An approach to the O2 activating mononuclear non-heme Fe enzymes: structural characterization
of Fe(II)-acetato complex and formation of alkylperoxoiron(III) species
with the highly hindered hydrotris(3-tert-butyl-5-isopropyl-1-pyrazolyl)borate”
Inorg. Chim. Acta, 297, 162-170 (2000).
Koyu Fujita, Shiro Hikichi, Munetaka Akita, Yoshihiko Moro-oka
“Novel monoanionic tripodal ligands: methylbis(1-methylimidazol-2-yl)(pyrazol-1-yl)borate (= MeB(ImN-Me)2(PzR)]-). Synthesis and structural characterization of their nickel complexes and carboxylate shift from nickel to boron”
J. Chem. Soc., Dalton Trans., 117-120 (2000).
Yoshiaki Takahashi, Mariko Hashimoto, Shiro Hikichi, Munetaka Akita, Yoshihiko Moro-oka
“Conversion of Molecular Oxygen into a Hydroperoxo Species by Ring-Opening
Protonation of a Cyclic η2-Peroxide Intermediate: Characterization of the η2-Peroxide and Hydroperoxo Complexes”
Angew. Chem. Int. Ed., 38, 3074-3076 (1999).
Shiro Hikichi, Michito Yoshizawa, Yasuyuki Sasakura, Yoshihiko Moro-oka, Munetaka Akita
“Oxygenation of Saturated Hydrocarbyl Groups in the Dinuclear Ni(III) Bis(μ-oxo) Complexes with the Hydrotris(pyrazolyl)borate Ligands TpR (R = Me3 and Pri2)”
Chem. Lett., 28, 979-980 (1999).
Munetaka Akita, Taichi Miyaji, Shiro Hikichi, Yoshihiko Moro-oka
“A Transition Metal-Hydroperoxo Complex Stabilized by Hydrogen-Bonding
Interaction: The First Example of a Hydroperoxopalladium Species Characterized
by X-Ray Crystallography, (κ2-TpiPr)Pd(PPh3)(OOH) [TpiPr = hydrotris(3,5-diisopropylpyrazolyl)borato]”
Chem. Lett., 28, 813-814 (1999).
Yoshiaki Takahashi, Shiro Hikichi, Munetaka Akita, Yoshihiko Moro-oka
“Oxidative C(sp3)-C(sp3) bond cleavage reaction of an isopropyl group to give an acetyl group
via O2-treatment of a labile cationic ruthenium species, [TpiPrRu(dppene)(OH2)]+”
Chem. Commun., 1491-1492 (1999).
Keisuke Ohta, Mariko Hashimoto, Yoshiaki Takahashi, Shiro Hikichi, Munetaka Akita, Yoshihiko Moro-oka
“Synthesis of a Series of Rhodium Complexes, TpiPrRhIL2 and TpiPrRhIII(X)(Y)(MeCN), with Hydrotris(3,5-diisopropyl-pyrazolyl)borato Ligand (TpiPr) from the Versatile Precursor, (κ3-TpiPr)Rh(coe)(MeCN), and Dependence of the κ2-κ3 Interconversion Rate of the TpiPr Ligand on the Chelate Ring Size”
Organometallics, 18, 3234-3240 (1999).
Yoshiaki Takahashi, Shiro Hikichi, Munetaka Akita, Yoshihiko Moro-oka
“A Coordinatively Unsaturated Species with Agostic C-H Interaction, [κ4-TpiPrRu(dppe)]OSO2CF3, and its Addition Reaction”
Organometallics, 18, 2571-2573 (1999).
Masahiro Kosugi, Shiro Hikichi, Munetaka Akita, Yoshihiko Moro-oka
“The first evidence for activation of exogenous O2 on a vanadium(IV) center: Synthesis and characterization of a peroxo vanadium(V) complex with hydrotris(3,5-diisopropyl-1-pyrazolyl)borate”
J. Chem. Soc., Dalton Trans., 1369-1372 (1999).
Masahiro Kosugi, Shiro Hikichi, Munetaka Akita, Yoshihiko Moro-oka
“Inter- and Intramolecular Hydrogen-bonding Interaction of Hydroxo Groups
and Steric Effect of Alkyl Substituents on Pyrazolyl Rings in TpR Ligands: Synthesis and Structural Characterization of Chloro- and Hydroxo
Complexes of VO2+ with TpPri2 and TpMe2 Ligands”
Inorg. Chem., 38, 2567-2578 (1999).
Munetaka Akita, De-qiang Ma, Shiro Hikichi, Yoshihiko Moro-oka
“Synthesis and crystal structures of mononuclear half-sandwich Ni and Co complexes containing the Klaui's tripodal ligand, [κ3-(η5-C5H5)Co{P(=O)(OCH3)2}3]M(κ2-NO3)(L) (M= Ni, Co)”
J. Chem. Soc., Dalton Trans., 987-996 (1999).
Nobuhiko Shirasawa, Munetaka Akita, Shiro Hikichi, Yoshihiko Moro-oka
“Thermally stable coordinatively unsaturated alkyl complexes resistant
to β-hydride elimination: TpiPrM-CH2CH3 (M = Co, Fe)”
Chem. Commun., 417-418 (1999).
Hidehito Komatsuzaki, Naoko Sakamoto, Minoru Satoh, Shiro Hikichi, Munetaka Akita, Yoshihiko Moro-oka
“The First Synthesis and Structural Characterization of Alkylperoxo Complex of Mn(II)”
Inorg. Chem., 37, 6554-6555 (1998).
Yoshiaki Takahashi, Munetaka Akita, Shiro Hikichi, Yoshihiko Moro-oka
“Two Isomeric Structures of Hydridoruthenium Complexes Supported by Hydrotrispyrazolylborates,
TpRRu(H)(1,5-cyclooctadiene): An Octahedral Structure with Additional 3-Center-2-Electron Ru-H-B Interaction Is More Stable than a Square-Pyramidal Structure with a κ2-TpR Ligand”
Organometallics, 17, 4884-4888 (1998).
Shiro Hikichi, Michito Yoshizawa, Yasuyuki Sasakura, Munetaka Akita, Yoshihiko Moro-oka
“First Synthesis and Structural Characterization of Dinuclear M(III) Bis(μ-oxo)
Complexes of Nickel and Cobalt with Hydrotris(pyrazolyl)borate Ligand”.
J. Am. Chem. Soc., 120, 10567-10568 (1998).
Hidehito Komatsuzaki, Shinobu Ichikawa, Shiro Hikichi, Munetaka Akita, Yoshihiko Moro-oka
“Characterization of a Dinuclear Mn(II) (μ-Hydroxo)(μ-Pyrazolato) Complex
and Hydrolytic Equilibrium of the Bridging Pyrazolate Ligand”
Inorg. Chem., 37, 3652-3656 (1998).
Yoshiaki Takahashi, Munetaka Akita, Shiro Hikichi, Yoshihiko Moro-oka
“Synthesis of Various Cationic Ruthenium-Aqua Complexes with the Hydrotris(3,5-diisopropylpyrazolyl)borate
Ligand, TpiPrRu(OH2)n(L)3-n(CF3SO3)(THF)x, and Their Structures Supported by Hydrogen-Bonding Networks”
Inorg. Chem., 37, 3186-3194 (1998).
Tamako Ogihara, Shiro Hikichi, Munetaka Akita, Yoshihiko Moro-oka
“Synthesis, Structural Characterization, and Extradiol Oxygenation of Iron-Catecholato Complexes with Hydrotris(pyrazolyl)borate Ligands”
Inorg. Chem., 37, 2614-2615 (1998).
Shiro Hikichi, Hidehito Komatsuzaki, Munetaka Akita, Yoshihiko Moro-oka
“Aliphatic C-H Bond Oxygenation by the CoIIOOX Species with the Hindered Hydrotris(pyrazolyl)borate Ligand (X = Co(II),
Alkyl, H)”
J. Am. Chem. Soc., 120, 4699-4710 (1998).
Munetaka Akita, Taichi Miyaji, Shiro Hikichi, Yoshihiko Moro-oka
“Systematic synthesis of a series of hydroperoxo- alkylperoxo- and μ-peroxo-palladium complexes supported by the hydrotris(3,5-diisopropylpyrazolyl)borate ligand (TpiPr), TpiPrPd(py)-OOX [X = PdTpiPr(py), H, But], via dehydrative condensation of a hydroxo complex, TpiPrPd(py)-OH”
Chem. Commun., 1005-1006 (1998).
Munetaka Akita, Nobuhiko Shirasawa, Shiro Hikichi, Yoshihiko Moro-oka
“14e η1-Hydrocarbyliron complexes supported by hydrotris(3,5-diisopropylpyrazolyl)borate: the allyl complex prefers a highly coordinatively unsaturated 14e η1-structure to a 16e η3-structure”
Chem. Commun., 973-974 (1998).
Hidehito Komatsuzaki, Yuichi Nagasu, Kantaro Suzuki, Takao Shibasaki, Minoru Satoh, Fujio Ebina, Shiro Hikichi, Munetaka Akita, Yoshihiko Moro-oka
“Dioxygen activation by a novel manganese(II) thiolate complex with hydrotris(3,5-diisopropylpyrazol-1-yl)borate ligand”
J. Chem. Soc., Dalton Trans., 511-512 (1998).
Munetaka Akita, Keisuke Ohta, Yoshiaki Takahashi, Shiro Hikichi, Yoshihiko Moro-oka
“Synthesis and Structure Determination of Rh-diene Complexes with the Hydridotris(3,5-diisopropylpyrazolyl)borate Ligand, TpiPrRh(diene) (diene = cod, nbd): Dependence of the ν(B-H) Values on the Hapticity
of the TpiPr Ligand (κ2 vs κ3)”
Organometallics, 16, 4121-4128 (1997).
Shiro Hikichi, Tamako Ogihara, Kiyoshi Fujisawa, Nobumasa Kitajima, Munetaka Akita, Yoshihiko Moro-oka
“Synthesis and Characterization of the Benzoylformato Ferrous Complexes with the Hindered Tris(pyrazolyl)borate Ligand as a Structural Model for Mononuclear Non-Heme Iron Enzymes”
Inorg. Chem., 36, 4539-4547 (1997).
Shiro Hikichi, Hidehito Komatsuzaki, Nobumasa Kitajima, Munetaka Akita, Masahiro Mukai, Teizo Kitagawa, Yoshihiko Moro-oka
“Characterization of a μ-η2:η2-Peroxo Dinuclear Cobalt(II) Complex”
Inorg. Chem., 36, 266-267 (1997).
Nobumasa Kitajima, Hidehito Komatsuzaki, Shiro Hikichi, Masahisa Osawa, Yoshihiko Moro-oka
“A Monomeric Side-On Peroxo Manganese(III) Complex: Mn(O2)(3,5-iPr2pzH)(HB(3,5-iPr2pz)3)”
J. Am. Chem. Soc., 116, 11596-11597 (1994).
Shiro Hikichi, Masako Tanaka, Yoshihiko Moro-oka, Nobumasa Kitajima
“Reaction of Hydroxo Complexes of Divalent Metal Ions with Amide”
J. Chem. Soc., Chem. Commun., 1737-1738 (1994).
Nobumasa Kitajima, Kiyoshi Fujisawa, Shiro Hikichi, Yoshihiko Moro-oka
“Formation of (μ-Hydroxo)(μ-azido) Dinuclear Copper Complex from μ-η2:η2-Peroxo Complex”
J. Am. Chem. Soc., 115, 7874-7875 (1993).
Nobumasa Kitajima, Shiro Hikichi, Masako Tanaka, Yoshihiko Moro-oka
“Fixation of Atmospheric CO2 by a Series of Hydroxo Complexes of Divalent Metal Ions and the Implication for the Catalytic Role of Metal Ion in Carbonic Anhydrase. Synthesis, Characterization, and Molecular Structure of [LM(OH)]n (n = 1 or 2) and LM(μ-CO3)ML (M(II) = Mn, Fe, Co, Ni, Cu, Zn; L = HB(3,5-iPr2pz)3)”
J. Am. Chem. Soc., 115, 5496-5508 (1993).
Shiro Hikichi, Masako Tanaka, Yoshihiko Moro-oka, Nobumasa Kitajima
“Phosphate Ester Cleavage with a Zinc Hydroxo Complex. Formation and Crystal Structure of a Dinuclear Zinc Complex Bridged with a Phosphate Monoester”
J. Chem. Soc., Chem. Commun., 814-815 (1992).
Nobumasa Kitajima, Kiyoshi Fujisawa, Takayuki Koda, Shiro Hikichi, Yoshihiko Moro-oka
“Fixation of Atmospheric CO2 by a Copper(II) Complex”
J. Chem. Soc., Chem. Commun., 1357-1358 (1990).
2. 総説等
Noritaka Mizuno, Shiro Hikichi, Kazuya Yamaguchi, Sayaka Uchida, Yoshinao Nakagawa, Kazuhiro Uehara, Keigo Kamata
“Molecular design of selective oxidation catalyst with polyoxometalate”
Catal Today, 117, 32-36 (2006).
引地 史郎
“人工酸化酵素の開発を指向した遷移金属―活性酸素錯体の研究”
神奈川大学工学研究所所報, 29号, 10-17 (2006).
引地 史郎
“生物無機化学と触媒化学の接点”
触媒, 46, 262-267 (2004).
Munetaka Akita, Shiro Hikichi
“Inorganic Chemistry Based on Tp Ligands - From Dioxygen Complexes to Organometallic Systems ?“
Bull. Chem. Soc. Jpn., 75, 1657-1679 (2002).
引地 史郎
“遷移金属-活性酸素錯体の合成と分子化学”
化学工業, 53, 410-415 (2002).
Shiro Hikichi, Munetaka Akita, Yoshihiko Moro-oka
“New aspects of the cobalt-dioxygen complex chemistry opened by hydrotris(pyrazoly)borate
ligands (= TpR): Unique properties of TpRCo-dioxygen complexes”
Coord. Chem. Rev., 198, 61-87 (2000).
穐田 宗隆, 引地 史郎, 諸岡 良彦
“ヒドロトリス（ピラゾリル）ボレートを配位子とする金属錯体の化学 -酸素錯体を中心に-”
有機合成化学協会誌, 57, 619-628 (1999).
Munetaka Akita, Kiyoshi Fujisawa, Shiro Hikichi, Yoshihiko Moro-oka
“Chemistry of μ-η2:η2-Peroxo Dimetal Complexes: A Bioinorganic Model Triggers a New Trend of
Transition Metal Peroxo Species”
Res. Chem. Intermed., 24, 291-307 (1998).
3. 著書、編書
引地 史郎
“UNIT IV 化学量論 （10章 モルの概念，11章 化学反応式）”
小林・三五・中村・南澤・山口編著 「化学の世界への招待」，三共出版 (2009)；pp. 81-95.
引地 史郎
“錯体反応の速度と機構”（I, 基礎編 [3]均一系触媒反応の速度と反応機構3.2）
触媒学会編 「触媒便覧」，講談社サイエンティフィク (2008)；pp. 33-46.
引地 史郎
“錯体触媒による炭化水素類への環境調和型酸素添加反応”（3.研究動向 [4]有機化学）
触媒学会編 「触媒技術の動向と展望2008」，触媒学会 (2008)；pp. 40-50.
引地 史郎
“メタンモノオキシゲナーゼの反応機構と酵素模倣型アルカン選択酸化反応”（第5章2）
市川 勝 監修 「メタン高度化学変換技術集成」，シーエムシー出版 (2008)；pp. 343-356.
引地 史郎
“非ヘム金属酸化酵素”（6.3）
穐田 宗隆, 伊東 忍, 小夫家 芳明, 榊 茂好, 実川 浩一郎, 鈴木 正樹, 福住 俊一, 舩橋 靖博, 引地 史郎, 増田 秀樹, 山内
脩, 渡辺 芳人 共著 「生物無機化学（錯体化学会選書1）初版第二刷」，三共出版 (2005)；pp. 247-275.
引地 史郎
“典型元素と有機金属化学との比較”（15章）
“生物無機化学と環境化学”（16章）
内本 喜晴, 金村 聖志, 小宮 三四郎, 引地 史郎, 山瀬 利博, 脇原 將孝 訳 「ミースラー・タール無機化学I・II」，丸善 (2003)；pp.
703-792.
4. 解説記事等
引地 史郎
“金属タンパク質・酵素における金属中心の構造と機能”
固体物理, 43, 733-742 (2008).
引地 史郎
“炭化水素への酸素添加における反応選択性制御”
Organometallic News, 118 (2008).
引地 史郎
“水中で機能するメタン水酸化触媒”
化学, 60, (1) 66-67 (2005).
引地 史郎
“物理化学実験-反応速度論の体験的理解-”
化学と教育, 51, 470-473 (2003).
引地 史郎
“構造から機能へ-生物無機化学の新たな展開”
化学, 57, (9) 59-60 (2002).
引地 史郎
“複核遷移金属中心上での酸素活性化-高原子価オキソ種の生成-”
触媒, 41, 230 (1999).
5. その他
引地 史郎
“講演デビューと「仰げば尊し」（国際学会での武勇伝)”
化学, 63, (3) 527 (2008).
引地 史郎
“生活習慣と実験技術（会員の声)”
触媒, 49, 601-602 (2007).
6. 受賞
“遷移金属-活性酸素錯体の合成と分子化学的研究”
日本化学会進歩賞，2001年3月
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